The extraction of zirconium and hafnium from hydrochloric acid media was studied using the crown ethers dibenzo-18-crown-6 (DB18C6), dicyclohexano-18-crown-6 (DC18C6) and dicyclohexano-24-crown-8 (DC24C8) as extractants...
Keywords: Zirconium, Hafnium, Crown ether, Liquid-liquid extraction, Distribution ratio
03/2006 | Radiochimica Acta, Oldenbourg WissenschaftsverlagA process of step-wise complexation of group-4 elements Zr, Hf, and Rf in H2SO4 solutions has been considered theoretically...
Keywords: Zirconium, Hafnium, Rutherfordium, Complex formation, Relativistic density functional theory
08/2006 | Radiochimica Acta, Oldenbourg WissenschaftsverlagThe solubility of zirconium(IV) hydrous oxide was measured in the hydrogen ion concentration (pHc) range from 1 to 13 at 25 °C...
Keywords: Zirconium, Solubility, Size distribution, Colloid, Ultrafiltration
09/2006 | Radiochimica Acta, Oldenbourg WissenschaftsverlagWe report the results of the ablation of a zirconium rod in isopropyl alcohol employing a titanium sapphire femtosecond laser system operated at sub-800nm wavelengths with a fluence of 2mJ/pulse and a 10Hz pulse rate...
Keywords: laser ablation, Transition Metals, Nanoparticles, Zirconium, Colloids
11/2007 | Zeitschrift für Physikalische Chemie, Oldenbourg Wissenschaftsverlag