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Items for "Underpotential Deposition"

On a New Phase Transition in the Cu/Au(111)/H2SO4 System

A new pair of current spikes has been found in the cyclic voltammogram of Au(111) in an acidic copper sulphate solution, indicative of a phase transition in the Cu adlayer...

Keywords: Au(111), Cu, Cyclic voltammetry, Phase transition, Underpotential Deposition

11/2007 | Zeitschrift für Physikalische Chemie, Oldenbourg Wissenschaftsverlag
Microcalorimetry of Electrochemical Reactions at Submonolayer Conversions

We measured heat effects upon underpotential deposition or dissolution of a fraction of a monolayer of Cu on a Au surface...

Keywords: Electrochemistry, Calorimetry, Underpotential Deposition, Peltier Heat, Entropy of Electrode Reactions

11/2007 | Zeitschrift für Physikalische Chemie, Oldenbourg Wissenschaftsverlag
Electrodeposition methods in superheavy element chemistry

To prepare electrodeposition experiments with superheavy elements (SHE), their homologs were investigated...

Keywords: Electrodeposition, Underpotential Deposition, Critical potentials, Kinetics, Superheavy element chemistry

02/2008 | Radiochimica Acta, Oldenbourg Wissenschaftsverlag