The first total synthesis of plantamajoside (1), 2-(3?,4?-dihydroxylphenyl)ethyl-4-O-caffeoyl-3-O-(?-D-glucopyranosyl)-?-D-glucopyranoside, which is one of the dihydroxyphenylethyl glycosides (caffeic acid sugar esters), is described...
Keywords: dihydroxyphenylethyl glycoside, glycosidation, natural products, plantamajoside, total synthesis, trichloroacetimidate, wood extractives