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Items for "Stability constant"

Interaction of neptunium(V) with picolinic, nicotinic and isonicotinic acids

The interaction of Np(V) with all isomers of pyridinemonocarboxylic acid has been investigated, stability constants have been calculated using NIR spectroscopy...

Keywords: Neptunium, Crystal structure, Stability constant, Complexation, Spectrophotometry

02/2006 | Radiochimica Acta, Oldenbourg Wissenschaftsverlag
Thermodynamic study of metal silicate complexation in perchlorate media

The thermodynamic parameters of formation of the o-silicate complexes of UO22+, Cm3+ and Eu3+ have been measured in the temperature range 5−45 °C in an aqueous medium of 0.20 M NaClO4) ionic strength...

Keywords: Thermodynamics, Silicate, Complexation, Stability constant, Solvent extraction

02/2006 | Radiochimica Acta, Oldenbourg Wissenschaftsverlag
Protonation of D-gluconate and its complexation with Np(V) in acidic to nearly neutral solutions

Thermodynamic properties of the protonation of D-gluconic acid (HGH4(aq)) and its complexation with Np(V) have been studied in acidic to nearly neutral solutions at t =25 °C and I=1 M NaClO4 by potentiometry, spectrophotometry and calorimetry...

Keywords: Gluconic acid, Neptunium, Complexation, Stability constant, Enthalpy

09/2006 | Radiochimica Acta, Oldenbourg Wissenschaftsverlag
Extraction Distribution of Sodium Picrate in the Water–Nitrobenzene System in the Presence of p-tert-Butylcalix[4]arene-tetrakis(N,N-diethylacetamide)

From extraction experiments with 22Na as a tracer, the extraction constant corresponding to the equilibrium Na+(aq) + A-(aq) + L(nb) ↔ NaL+(nb) + A-(nb) taking place in the two-phase water–nitrobenzene system [A- = picrate, L = p-tert -butylcalix[4]arene-tetrakis(N,N-diethylacetamide); aq = aqueous phase, nb = nitrobenzene phase] was evaluated as log Kex(NaL+, A-) = 4.6± 0.1...

Keywords: Sodium Picrate, Calix[4]arene Compound, Extraction, Water–Nitrobenzene System, Stability constant

12/2006 | Zeitschrift für Physikalische Chemie, Oldenbourg Wissenschaftsverlag