Items for "rapid-mixing/freeze-quench"

Spectroscopic characterization of the iron-oxo intermediate in cytochrome P450

From analogy to chloroperoxidase from Caldariomyces fumago, it is believed that the electronic structure of the intermediate iron-oxo species in the catalytic cycle of cytochrome P450 corresponds to an iron(IV) porphyrin-?-cation radical (compound I)...

Keywords: compound I, Mössbauer spectroscopy, multi-frequency EPR, radicals, rapid-mixing/freeze-quench, thiolate heme proteins