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Items for "Phase transition"

Ag6GeS4X2 (X: Cl, Br): surprisingly no filled Laves phases but the first representatives of a new structure type

The two new deeply coloured, air stable, isotypic compounds Ag6GeS4X2 (X: Cl, Br) were obtained in the course of a series of experiments to prepare new “non-metallic filled Laves phases (= argyrodites)”...

Keywords: Argyrodite, Laves phase, Topological close packing, Phase transition, Single crystal structure analysis

05/2006 | Zeitschrift für Kristallographie, Oldenbourg Wissenschaftsverlag
Low- and high-temperature structures of YbCuBi

A variable temperature single-crystal X-ray diffraction study was undertaken on the intermetallic compound YbCuBi, which undergoes a phase transition at ∼375 K...

Keywords: Phase transition, Bismuth, Intermetallics, Single crystal structure analysis, X-ray diffraction

05/2006 | Zeitschrift für Kristallographie, Oldenbourg Wissenschaftsverlag
The Difference in Entropy Between a Stable and Metastable Phase as the Temperature Approaches Zero Kelvin

The free energy of two different phases not in equilibrium at the limit of zero Kelvin must be different...

Keywords: Heat Capacity, Equilibrium, Zero Kelvin, Nernst Heat Theorem, Phase transition

06/2006 | Zeitschrift für Physikalische Chemie, Oldenbourg Wissenschaftsverlag
Crystal structures of high-pressure phases in the alumina-water system: I. Single crystal X-ray diffraction and molecular dynamics simulation of η-Al(OH)3

The high-pressure phase of gibbsite has been studied by in situ single crystal X-ray diffraction method and molecular dynamics (MD) simulation at 3.0 GPa...

Keywords: Gibbsite, High pressure, Phase transition, Single crystal structure analysis, X-ray diffraction

01/2007 | Zeitschrift für Kristallographie, Oldenbourg Wissenschaftsverlag
On a New Phase Transition in the Cu/Au(111)/H2SO4 System

A new pair of current spikes has been found in the cyclic voltammogram of Au(111) in an acidic copper sulphate solution, indicative of a phase transition in the Cu adlayer...

Keywords: Au(111), Cu, Cyclic voltammetry, Phase transition, Underpotential Deposition

11/2007 | Zeitschrift für Physikalische Chemie, Oldenbourg Wissenschaftsverlag
Thermodynamic and Structural Investigations of Condensates of Small Molecules in Mesopores

Liquids and solids consisting of small, mainly van-der-Waals interacting building blocks, such as Ar, Kr, N2, O2, and CO, are among the most simple systems of condensed matter imaginable...

Keywords: Mesopores, Phase transition, Capillary Condensation, Capillary Sublimation

02/2008 | Zeitschrift für Physikalische Chemie, Oldenbourg Wissenschaftsverlag