Items for "Organic acid"

Determination of the thermodynamic quantities of complexation between Eu(III) and carboxylic acids by microcalorimetry

Potentiometric and microcalorimetric titration techniques were applied to determine the Gibbs free energies and enthalpies of the protonation of some carboxylic acids (acetic, glycolic, malonic and malic acids) and their complexation with Eu(III) in 1.0 M NaClO₄ solution at 25 °C, where Eu(III) was used as a chemical analogue of radiologically important Am(III)...

Keywords: Calorimetry, Eu(III), Organic acid, Complex formation, Entropy