Items for "nonadiabatic coupling"

Long Range Nonadiabatic Couplings and the Cluster-Size Dependence of the Lifetime of Excited Hydrated Electrons

The recently observed linear dependence of the lifetime of excited hydrated electrons upon the inverse of the cluster size is explained in terms of a nonadiabatic long range coupling mechanism...

Keywords: excited hydrated electrons, anion water clusters, internal conversion, nonadiabatic coupling, solvation dynamics