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Items for "Hydrolysis"

Hydrolysis of plutonium(IV) in acidic solutions: no effect of hydrolysis on absorption-spectra of mononuclear hydroxide complexes

Tetravalent plutonium readily undergoes hydrolysis even in highly acidic aqueous solutions. In the past, many attempts were made to quantify hydrolysis species by means of optical absorption spectroscopy...

Keywords: Plutonium, Tetravalent, Hydrolysis, Redox reaction, Disproportionation

01/2007 | Radiochimica Acta, Oldenbourg Wissenschaftsverlag
Investigation of the hydrolysis of plutonium(IV) by a combination of spectroscopy and redox potential measurements

The hydrolysis of tetravalent plutonium in 0.5 M HCl/NaCl has been investigated by a combination of spectroscopy and redox potential measurements in the concentration range from 10-5 to 4×10-4 M and at pHc 0.3–2.1...

Keywords: Plutonium(IV), Hydrolysis, Formation constants, Redox potential, Spectroscopy

02/2007 | Radiochimica Acta, Oldenbourg Wissenschaftsverlag
Degradation of polyethylene glycol and hemicellulose in the Vasa

Mass spectrometric analysis of aqueous wood extracts from the Swedish warship Vasa reveals a serious chemical condition in the depth of the wood...

Keywords: catalytic oxidation, hemicelluloses, Hydrolysis, matrix-assisted laser desorption/ionization-time of flight (MALDI-TOF), polyethylene glycol, Vasa, wood degradation

01/2008 | Holzforschung, Walter de Gruyter