Science.Online
Search
Publisher and Institutes
Akademie Verlag
Deutsches Institut für Urbanistik
Oldenbourg Wissenschaftsverlag
Walter de Gruyter
Schattauer
You are here: Home :: Keyword index :: gen bis Hyd :: hybrid design - Hydrolysis hydrogen abstraction

Items for "hydrogen abstraction"

Spectroscopic and theoretical approaches for studying radical reactions in class I ribonucleotide reductase

Ribonucleotide reductases (RNRs) catalyze the production of deoxyribonucleotides, which are essential for DNA synthesis and repair in all organisms...

Keywords: amino acid-based radicals, catalytic mechanism, Density functional theory, high-field EPR/ENDOR, hydrogen abstraction, ribonucleotide reductase

10/2005 | Biological Chemistry, Walter de Gruyter
A selectivity study of reaction of the carbonate radical anion with methyl ?-d-cellobioside and methyl ?-d-glucoside in oxygenated aqueous solutions

In the presence of oxygen, radiolytically generated carbonate radical anions, CO3?–, were reacted with methyl ?-D-cellobioside and methyl ?-D-glucoside...

Keywords: carbohydrate, carbonate radical, glucosidic cleavage, hydrogen abstraction, intramolecular, model compounds, selectivity

03/2006 | Holzforschung, Walter de Gruyter