Alkali metal uranyl chloride (M2UO2Cl4 (M = Na or Cs)) was dissolved in 1-butyl-3-methylimidazolium chloride (bmimCl) and the redox behavior of uranyl ion present in the resultant solution was investigated by cyclic voltammetry at 343 K...
Keywords: Room temperature molten salts, Uranium, Electrodeposition, Cyclic voltammetry, Extraction
08/2006 | Radiochimica Acta, Oldenbourg WissenschaftsverlagElectrodeposition of a metal requires the reduction of metal ions by electrons and can in principle occur at any interface or in any boundary region between two electrically conducting phases with different ionic transference numbers...
Keywords: Electrodeposition, Electrode Processes, Interfaces, Cathodes, Cathodic Reduction
10/2006 | Zeitschrift für Physikalische Chemie, Oldenbourg WissenschaftsverlagIn this paper devoted to Professor Dieter Kolbīs 65th birthday the prospects and challenges of ionic liquids for fundamental investigations at the interface electrode/electrolyte are discussed...
Keywords: Ionic Liquids, In-Situ STM, Electrodeposition, Probing Impurities
09/2007 | Zeitschrift für Physikalische Chemie, Oldenbourg WissenschaftsverlagKinetic Monte Carlo (KMC) simulations were carried out to simulate kinetic-limited electrodeposition of a metal (M) onto an array of pre-existing metal clusters on a substrate (S) of a second conducting material...
Keywords: Metal Cluster, Nucleation, Kinetic Monte Carlo, Simulation, Electrodeposition
09/2007 | Zeitschrift für Physikalische Chemie, Oldenbourg WissenschaftsverlagTo prepare electrodeposition experiments with superheavy elements (SHE), their homologs were investigated...
Keywords: Electrodeposition, Underpotential Deposition, Critical potentials, Kinetics, Superheavy element chemistry
02/2008 | Radiochimica Acta, Oldenbourg Wissenschaftsverlag