Room temperature molten salts for possible application of recovery of fission palladium from irradiated nuclear fuel/wastes have been investigated...
Keywords: Room temperature ionic liquids, Recovery of palladium, Cyclic voltammetry, Electrorefining, Extraction
03/2006 | Radiochimica Acta, Oldenbourg WissenschaftsverlagThe redox behaviour of N,N-dimethyl-p-phenylenediamine (PPD) and N,N-dimethyl-p-phenylenediamine · 2HCl (PPD · 2HCl) in acetonitrile was studied by means of cyclic voltammetry – both in the absence and in the presence of proton accepting pyridine...
Keywords: Cyclic voltammetry, p-Phenylenediamine, Pyridine, Acid
04/2006 | Zeitschrift für Physikalische Chemie, Oldenbourg WissenschaftsverlagAlkali metal uranyl chloride (M2UO2Cl4 (M = Na or Cs)) was dissolved in 1-butyl-3-methylimidazolium chloride (bmimCl) and the redox behavior of uranyl ion present in the resultant solution was investigated by cyclic voltammetry at 343 K...
Keywords: Room temperature molten salts, Uranium, Electrodeposition, Cyclic voltammetry, Extraction
08/2006 | Radiochimica Acta, Oldenbourg WissenschaftsverlagIn this paper we report on some results on the electrochemical breakdown of ionic liquids at the cathodic limit of the electrochemical window and on the probing of inorganic impurities in ionic liquids (originating from the synthesis) at the interface electrode/electrolyte by in situ scanning tunneling microscopy on Au(111)...
Keywords: Ionic Liquids, Inorganic Impurities, In Situ STM, Cyclic voltammetry
10/2006 | Zeitschrift für Physikalische Chemie, Oldenbourg WissenschaftsverlagCatalytic reactions with different oxidation process were investigated and correlated to the electrochemical properties of the catalysts...
Keywords: Cyclic voltammetry, Suprafacial, Intrafacial, Heterogeneous Catalysis
12/2006 | Zeitschrift für Physikalische Chemie, Oldenbourg WissenschaftsverlagA new pair of current spikes has been found in the cyclic voltammogram of Au(111) in an acidic copper sulphate solution, indicative of a phase transition in the Cu adlayer...
Keywords: Au(111), Cu, Cyclic voltammetry, Phase transition, Underpotential Deposition
11/2007 | Zeitschrift für Physikalische Chemie, Oldenbourg Wissenschaftsverlag