In the case of a rapid photochemical process, a new theoretical result relating time-resolved emission spectroscopy data to three physical parameters of the chemical system has been recently proposed...
Keywords: Fluorescence, Eu(III), Cm(III), Photochemistry, Equilibrium constant
05/2006 | Radiochimica Acta, Oldenbourg WissenschaftsverlagThe solvation of the Eu-perchlorate (ClO4–) and triflate (CF3SO3–, OTf–) salts as well as of Cm(ClO4)3 and Am(ClO4)3 in the ionic liquid C4mimTf2N (1-butyl-3-methylimidazolium-bis(trifluoromethylsulfonyl)imide) has been comparatively investigated by application of laser fluorescence spectroscopy and X-ray absorption spectroscopy...
Keywords: Ionic Liquids, Lanthanides, Actinides, Eu(III), Cm(III)
01/2008 | Radiochimica Acta, Oldenbourg Wissenschaftsverlag