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Items for "Cm(III)"

Experimental evidence for the influence of the excitation wavelength on the value of the equilibrium constant as determined by Time-Resolved Emission Spectroscopy (TRES)

In the case of a rapid photochemical process, a new theoretical result relating time-resolved emission spectroscopy data to three physical parameters of the chemical system has been recently proposed...

Keywords: Fluorescence, Eu(III), Cm(III), Photochemistry, Equilibrium constant

05/2006 | Radiochimica Acta, Oldenbourg Wissenschaftsverlag
TRLFS and EXAFS investigations of lanthanide and actinide complexation by triflate and perchlorate in an ionic liquid

The solvation of the Eu-perchlorate (ClO4) and triflate (CF3SO3, OTf) salts as well as of Cm(ClO4)3 and Am(ClO4)3 in the ionic liquid C4mimTf2N (1-butyl-3-methylimidazolium-bis(trifluoromethylsulfonyl)imide) has been comparatively investigated by application of laser fluorescence spectroscopy and X-ray absorption spectroscopy...

Keywords: Ionic Liquids, Lanthanides, Actinides, Eu(III), Cm(III)

01/2008 | Radiochimica Acta, Oldenbourg Wissenschaftsverlag