Both electrochemical (at Pt electrode) and homogeneous (with Cl2(aq)) oxidation of the aqueous solution of Ni(II)-N3− yields the solution of a brown product that was found to be the azide complex of Ni(IV)...
Keywords: Nickel(IV)-Azide Complexes, Azide Oxidation, Kinetic Parameters, Spectroscopic Properties, Charge-Transfer Spectrum
08/2006 | Zeitschrift für Physikalische Chemie, Oldenbourg Wissenschaftsverlag