Crystal data for natural and synthetic arsenic sulfides are reported and discussed. Most of them [α- and β-dimorphite, realgar, β-As4S4 phase, pararealgar, Kutoglu’s As4S4(II) phase, alacranite, uzonite, orthorhombic As4S5 phase] have a crystal structure consisting of a packing of cage-like, covalently bonded As4Sn (n = 3, 4 and 5) molecules held together by weak interactions of van der Waals character...
Keywords: Arsenic sulfides, Crystal structure, Light-induced alteration, Arsenical pigments
01/2008 | Zeitschrift für Kristallographie, Oldenbourg Wissenschaftsverlag