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Anilines
Items for "Anilines"
Preferential Solvation Effects on the Kinetics and Thermodynamics of Oxidation of Anilines by Chromium(VI)
The imidazolium fluorochromate (IFC) oxidation of fifteen meta - and para-substituted anilines, in varying mole fractions of benzene in 2-methylpropan-2-ol as mixtures, in the presence of p-toluenesulfonic acid (TsOH) is first order in IFC and TsOH and zero order in substrate...
Keywords: Anilines, Chromium(VI), Kinetics, Thermodynamics, Oxidation
06/2006 | Zeitschrift für Physikalische Chemie, Oldenbourg WissenschaftsverlagKinetic characterization of phenol and aniline derivates as substrates of peroxidase
The kinetic characterization of horseradish peroxidase (HRPC) substrates is difficult because the reaction products are free radicals...
Keywords: Anilines, ascorbic acid, free radicals, peroxidase, Phenols, steady-state kinetics
09/2004 | Biological Chemistry, Walter de GruyterInterpretation of the reactivity of peroxidase compound II with phenols and anilines using the Marcus equation
The catalytic cycle of heme peroxidases involves three processes: the formation of compound I, its conversion to compound II and regeneration of the native enzyme...
Keywords: Anilines, ascorbic acid, Marcus equation, peroxidase, Phenols, Reaction mechanism
04/2005 | Biological Chemistry, Walter de Gruyter