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D. Bedeaux, F. Standaert, K. Hemmes, S. Kjelstrup
Optimization of Processes by Equipartition
We examine the problem of energy-efficient production in an industrial process. By energy-efficient we mean minimum entropy production. We use the possibility to redistribute the production in different times or parts of the system for a given total production, and show that a distribution, that equipartitions the derivative of the local entropy production rate with respect to the local production, minimizes the entropy production. Equipartition in time implies stationary state production. Equipartition in space implies production for a given position independent force. The same constant derivative of the local entropy production rate is found if ones optimizes the production for a given total entropy production.
Close of equilibrium the equipartition condition is found to reduce to the isoforce principle. Further from equilibrium, this reduction is extended to a whole class of nonlinear flux-force relations. We show that, when one increases the total production, the entropy production per unit produced starts to increase linearly, as a function of this total production.
It is shown which process conditions give an optimum path with an equipartition of the entropy production rate. How this relates to the isoforce principle is discussed. In general constraints on process conditions restrict the freedom to optimize, and therefore make it impossible to realise the most favorable conditions. The importance of the Onsager relations for the systematic description of the optimization is discussed.
Journal of Non-Equilibrium Thermodynamics, Walter de Gruyter
Print ISSN: 0340-0204
Volume: 24, 12/1999
Pages: 242 - 259