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D. Bedeaux, S. Kjelstrup

Local Properties of a Formation Cell as Described by Nonequilibrium Thermodynamics

The current description of a formation cell using nonequilibrium thermodynamics gives an overall picture. It does not consider the behaviour of the temperature, chemical potential and electric potential locally. Thus it is unclear where temperature and potential change in the cell. Are these quantities discontinuous at the electrode surfaces, and if yes: how this should be described. Using methods developed in our earlier work we present such a local description. A differential equation is derived and solved for the transference coefficient of the salt in the electrolyte between the electrodes. Boundary conditions are essential for this purpose.

Journal of Non-Equilibrium Thermodynamics, Walter de Gruyter

Print ISSN: 0340-0204
Volume: 25, 09/2000
Pages: 161 - 178

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