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W. J. Nellis, R. Chau, Peter P. Edwards, Roland Winter
The Transition to the Metallic State in Alkali and Low-Z Fluids
We review here experiments that investigate how the electronic properties of five chemically dissimilar fluid elements, hydrogen, nitrogen, oxygen, rubidium and caesium, vary with density beyond their critical points. Remarkably, all five elements in their metallic regime have essentially the same electrical conductivities, close to the predicted minimum metallic conductivity of a high-temperature, disordered metallic fluid. The large differences in their respective metal-nonmetal transition densities are rationalized in terms of each chemical element′s unique atomic properties of size (radial extent of electronic wave function, N.F.Mott[1]) and electronic polarizability (K.F.Herzfeld and D.A.Goldhammer[2]). These experiments thereby highlight the pivotal role of atomic properties in dictating the metallic or nonmetallic status of chemical elements of the periodic classification.
Zeitschrift für Physikalische Chemie, Oldenbourg Wissenschaftsverlag
Print ISSN: 0942-9352
Volume: 217, 07/2003
Pages: 795