You are here: Home :: Area NEM :: Chemistry :: Physical chemistry

W.-C. Luo, J.-L. Lay, Jenn-Shing Chen

NMR Study of Hydrogen Bonding Association of 2-Isopropylphenol in Carbon Tetrachloride, Acetone, Dimethyl Sulphoxide and Acetonitrile

This study investigates the association of 2-isopropylphenol through hydrogen bonding in carbon tetrachloride, [²H₆]acetone, [²H₃]acetonitrile and [²H₆]dimethyl sulphoxide by using high resolution nuclear magnetic resonance spectroscopy. Chemical shifts of the hydroxyl proton were measured over a wide range of temperature and concentration. The chemical shift data were treated by a graphical method to determine the monomer shift, dimer shift and dimerization constant. The enthalpy and entropy of dimerization were determined via a van´t Hoff plot from the temperature variation of the dimerization constant.

Zeitschrift für Physikalische Chemie, Oldenbourg Wissenschaftsverlag

Print ISSN: 0942-9352
Volume: 215, 01/2001
Pages: 001

Journal homepage (external site)

Show all available items of this journal

 

Area NEM