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Hannelore Katzke, R. Schlögl

General structural relationships between rutile-type VO2 and the Magnéli-phases VnO2n–1

The structures of the Magnéli-phases VnO2n–1 (3 ≤ n ≤ 7) are reviewed with respect to their structural relationships to rutile-type VO2. The general expressions for the transformation matrices P and Q = P–1 are derived allowing the prediction of lattice parameters and atomic coordinates for hypothetical structures of VnO2n–1 with n ≥ 8.

Zeitschrift für Kristallographie, Oldenbourg Wissenschaftsverlag

Print ISSN: 0044-2968
Volume: 218, 06/2003
Pages: 432

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