You are here: Home :: Area NEM :: Chemistry :: Physical chemistry

Hong-Wen Gao, Jia-Xiang Yang, Jian-Fu Zhao

Establishment of Micellar Catalytic Field Using the p-Nitro-o-Carboxylbenzeneazo-8-Amino-quinoline – Cetyltrimethylammonium Bromide – Co(II) Ternary Complexation

The micellar catalytic field was proposed in surfactant medium by investigating the complexation between p-nitro-o-carboxylbenzeneazo-8-aminoquinoline (NCBAAQ) and Co(II) at pH 8.8. The cationic surfactant, cetyl trimethylammonium bromide (CTAB) was added and the aggregation of NCBAAQ on CTAB obeys the Langmuir isothermal adsorption. The enrichment of NCBAAQ on CTAB micelle resulted in a sensitive and rapid complexation of NCBAAQ with Co(II). The ternary complexation was characterized by the microsurface adsorption — spectral correction (MSASC) technique. Results showed that the complex Co₃NCBAAQ₁₂CTAB₇₈ is formed.

Zeitschrift für Physikalische Chemie, Oldenbourg Wissenschaftsverlag

Print ISSN: 0942-9352
Volume: 217, 11/2003
Pages: 1399

Journal homepage (external site)

Show all available items of this journal

 

Area NEM