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E.I. Dashevskaya, E.E. Nikitin

Correlation of Adiabatic States between Perturbed Rotor and Renner-Teller Limits for a Closed-Shell Ion + Open Shell Diatom System

The adiabatic channel interaction potentials for a system charge + dipole-open-shell-quadrupole linear rotor are calculated in the perturbed rotor and slightly anharmonic Renner-Teller limits. In both cases, first order charge-dipole and charge-quadrupole interactions are not additive; this leads to novel expressions for the energy levels. The result can be used in the construction of the adiabatic correlation diagrams between free rotor states with account for the Λ-doubling of a diatom and the linear anharmonic Renner-Teller triatomic system.

Zeitschrift für Physikalische Chemie, Oldenbourg Wissenschaftsverlag

Print ISSN: 0942-9352
Volume: 214, 08/2000
Pages: 1001

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