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Mohamed Merroun, Christoph Hennig, Andre Rossberg, T. Reich, Sonja Selenska-Pobell

Characterization of U(VI)-Acidithiobacillus ferrooxidans complexes using EXAFS, transmission electron microscopy, and energy-dispersive X-ray analysis

We used a combination of Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, Transmission Electron Microscopy (TEM) and Energy-Dispersive X-ray (EDX) analysis to conduct molecular scale studies on U(VI) interaction with three recently described eco-types of Acidithiobacillus ferrooxidans . On the basis of the information obtained by using these methods, we concluded that uranyl phosphate complexes were formed by the cells of the three eco-types studied. The uranium accumulated by A. ferrooxidans cells was located mainly within the extracellular polysaccharides, and on the cell wall. Smaller amounts were also observed in the cytoplasm.

Radiochimica Acta, Oldenbourg Wissenschaftsverlag

Print ISSN: 0033-8230
Volume: 91, 10/2003
Pages: 583

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