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Klára Keresztúri, István Szalai
Briggs–Rauscher Reaction with 1,4-Cyclohexanedione Substrate
Keywords: Nonlinear Dynamics, Oscillatory Reactions, Briggs–Rauscher Reaction, 1,4-Cyclohexanedione, Temperature Compensation
A new organic substrate has been used to promote oscillations under batch conditions in the Briggs–Rauscher oscillating system. The new substrate, 1,4-cyclohexanedione (CHD), reacts with aqueous iodine via an enol mechanism. We discuss the effect of the initial concentrations, the temperature and chemical perturbations. In a definite range of concentrations long-lived oscillations with two significantly different frequency periods were observed. The low frequency parts are temperature-dependent while the high frequency oscillations do not show temperature dependence. The inhibitory effects of 1,4-hydroquinone and 1,4-benzoquinone on the oscillations and the kinetics of some important component reactions were studied to develop a model for the simulation of the observed oscillations.
Zeitschrift für Physikalische Chemie, Oldenbourg Wissenschaftsverlag
Print ISSN: 0942-9352
Volume: 220, 08/2006
Pages: 1071 - 1082