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A.V. Kobelev, O.A. Kobelev, A.I. Sotnikov

Analysis of the Electrocapillary Curves and Adsorption Process Models in Copper||Boron + Aluminium Oxide Melt

We analyzed the electrocapillary curves (ecc) σ(φ) of pure copper and copper doped with 0.05 mass-% of sulfur at 1200 °C in contact with boron + aluminium oxide electrolyte. The influence of interface-active particles on electrocapillary features was analyzed using the Langmuir isotherm approximation taking into account competitive adsorption and the shift in the potential of zero charge (pzc).

Zeitschrift für Physikalische Chemie, Oldenbourg Wissenschaftsverlag

Print ISSN: 0942-9352
Volume: 203, 01/1998
Pages: 143

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