In this study, the reinforcing potential of cellulose “microfibres” obtained from bleached softwood kraft pulp was demonstrated in a matrix of polyvinyl alcohol (PVA). Microfibres are defined as fibres of cellulose of 0.1–1 ?m in diameter, with a corresponding minimum length of 5–50 ?m. Films cast with these microfibres in PVA showed a doubling of tensile strength and a 2.5-fold increase in stiffness with 5% microfibre loading. The theoretical stiffness of a microfibre was calculated as 69 GPa. The study also demonstrated that the strength of the composite was greater at 5% microfibre loading compared to 10% loading. Comparative studies with microcrystalline cellulose showed that the minimum aspect ratio of the reinforcing agent is more criticalthan its crystallinity in providing reinforcement in the composite.
Print ISSN: 0018-3830
Volume: 60, 01/2006
Pages: 53 - 58