M. Humar, M. Petri?, F. Pohleven, M. ?entjurc, P. Kalan
Changes of EPR Spectra of Wood Impregnated with Copper-Based Preservatives during Exposure to Several Wood-Rotting Fungi
Summary
The tolerance of various fungi against copper was examined. For this purpose, we impregnated Norway
spruce (Picea abies) specimens with two different aqueous solutions: copper(II) octanoate with
ethanolamine or copper(II) sulfate (cCu = 1.0 × 10?2 mol/l). Impregnated and unimpregnated test
specimens were then exposed to brown rot fungi Antrodia vaillantii and Gloeophyllum trabeum or
to white-rot fungi Schizophyllum commune and Trametes versicolor. After 2, 4, 6 and 12 weeks of
exposure Electron Paramagnetic Resonance, Atomic Absorption Spectroscopy and mass loss measurements
were performed. The results indicate that A. vaillantii, G. trabeum and T. versicolor transform
copper(II) sulfate in wood into non-soluble, and therefore non-toxic, copper oxalate. The
intensity of this reaction depends on the amount of excreted oxalic acid and was the highest for
A. vaillantii and the lowest for T. versicolor. In the presence of ethanolamine, formation of insoluble
copper oxalate was not possible and therefore, decay could not proceed. The major portion of copper
remained in the wood and only minor amounts were in some cases translocated into nutrient media.
Holzforschung, Walter de Gruyter
Print ISSN: 0018-3830
Volume: 56, 04/2002
Pages: 229 - 238
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